No you're doing it wrong on many levels
Not sure about your confusion with octane either. The 95/97/99 etc. is the octane rating or however you might describe it.
Up to you where you fill up, personally I just stick V-Power in mine, I'm not that bothered about the price difference of a couple of pence on the litre between stations. If you can afford to fill up (which is where most people base their comparisons, x amount for a full tank here, there, etc.) then you can afford what is IMO a negligible difference. The trend of pricing is what concerns me.
This topic has been covered before and depending who you ask some will tell you V-Power only if you have a JDM (edit: see, Pushki

not up on 4Gs but I know the 99+ UKDM 5G has a knock sensor so can IMO make optimum use of the higher octane), others will say it makes no difference if you use Tesco vs. BP. It's a can of worms.
But to get back on topic, don't keep using that booster stuff, maybe once every now and then. Just buy good quality fuel.